SYNTHESIS OF [PW9O37)FE3-XNIX(OAC)3(](9+X)- (X=PREDOMINANTLY-1) AND OXIDATION CATALYSIS BY THE CATALYST PRECURSOR

被引：45

作者：

MIZUNO, N

HIROSE, T

TATEISHI, M

IWAMOTO, M

机构：

[1] Hokkaido Univ, Sapporo, Japan

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 88卷 / 02期

关键词：

HETEROPOLYANION; KEGGIN-TYPE POLYANION; OXYGENATION; TRI-TRANSITION-METAL COMPLEX;

D O I：

10.1016/0304-5102(93)E0343-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Fe3-xNix-substituted Keggin-type heteropolyanion, [PW9O37{Fe3-xNix(OAc)3}](9+x)- (x = predominantly 1), was synthesized and characterized by elemental analysis, Mossbauer, H-1 NMR, magnetic moment, FAB mass, acid/base titration, and IR spectroscopy. The resulting catalyst precursor well catalyzed the selective oxidations of aldehydes, cyclohexene, and cyclohexane.

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页码：L125 / L131

页数：7

相关论文

共 45 条

[31] OXIDATION OF CYCLOHEXENE WITH HYDROGEN-PEROXIDE CATALYZED BY HETEROPOLY COMPOUNDS [J].

MIZUNO, N ;

YOKOTA, S ;

MIYAZAKI, I ;

MISONO, M .

NIPPON KAGAKU KAISHI, 1991, (08) :1066-1072

[32]

MIZUNO N, 1993, SHOKUBAI, V35, P150

[33] TEMPLATE-CONTROLLED FORMATION OF CLUSTER SHELLS OR A TYPE OF MOLECULAR RECOGNITION - SYNTHESIS OF [HV22O54(CLO4)]6- AND [H2V18O44(N3)]5- [J].

MULLER, A ;

KRICKEMEYER, E ;

PENK, M ;

ROHLFING, R ;

ARMATAGE, A ;

BOGGE, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1991, 30 (12) :1674-1677

[34] IRON-CATALYZED AND RUTHENIUM-CATALYZED OXIDATIONS OF ALKANES WITH MOLECULAR-OXYGEN IN THE PRESENCE OF ALDEHYDES AND ACIDS [J].

MURAHASHI, SI ;

ODA, Y ;

NAOTA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (20) :7913-7914

[35]

Pastor N. C., 1991, J AM CHEM SOC, V113, P5658

[36] A TRINUCLEAR, OXO-CENTERED MIXED-VALENCE IRON COMPLEX WITH UNPRECEDENTED CARBOXYLATE COORDINATION - [FE3O(O2CCH3)6(TACN)].2CHCL3 [J].

POGANIUCH, P ;

LIU, S ;

PAPAEFTHYMIOU, GC ;

LIPPARD, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (12) :4645-4651

[37]

Pope M. T., 1983, HETEROPOLY ISOPOLY O, V8

[38]

QU LY, 1988, TRANSIT METAL CHEM, V13, P183

[39]

RONG C, 1992, J AM CHEM SOC, V114, P29322

[40] SYNTHESIS, STRUCTURE, AND ELECTRONIC CHARACTERIZATION OF REACTIVE DIIRON(II) 1,2-BIS(2-HYDROXYBENZAMIDO)BENZENE COMPLEXES AS MODELS FOR METHANE MONOOXYGENASE [J].

STASSINOPOULOS, A ;

SCHULTE, G ;

PAPAEFTHYMIOU, GC ;

CARADONNA, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) :8686-8697

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