LIPASE MEDIATED DESYMMETRIZATION OF 1,2-BIS(HYDROXYMETHYL)FERROCENE IN ORGANIC MEDIUM - PRODUCTION OF BOTH ENANTIOMERS OF 2-ACETOXYMETHYL-1-HYDROXYMETHYLFERROCENE

被引：20

作者：

NICOLOSI, G

MORRONE, R

PATTI, A

PIATTELLI, M

机构：

[1] Istituto CNR per lo Studio delle Sostanze Naturali di Interesse Alimentare e Chimico-farmaceutico, 1-95028 Valverde, CT

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(00)80516-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Both enantiomers of 2-acetoxymethyl-1-hydroxymethylferrocene have been obtained via enantiotoposelective irreversible acylation in organic medium of 1,2-bis(hydroxymethyl)ferrocene using vinyl acetate as acyl donor and a lipase as catalyst.

引用

页码：753 / 758

页数：6

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