ENTHALPIES OF COMBUSTION OF EACH OF THE 2 BROMONAPHTHALENES

被引：47

作者：

DASILVA, MAVR

FERRAO, MLCCH

LOPES, AJM

机构：

[1] mica, Faculdade de Ciências, Universidade do Porto

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1993年 / 25卷 / 02期

关键词：

D O I：

10.1006/jcht.1993.1022

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The standard (p° = 0.1 MPa) molar enthalpies of combustion in oxygen at the temperature 298.15 K of the two bromonaphthalenes to form CO 2 (g), H 2 O(l), and Br 2 (l) were measured by rotating-bomb calorimetry. The standard molar enthalpy of sublimation at the temperature 198.15 K of 2-bromonaphthalene was measured by microcalorimetry. [[formula]] The derived standard molar enthalpies of formation of the gaseous compounds were compared with values estimated assuming the enthalpy increment for substitution of bromine in the 1-and 2-positions of naphthalene to be the same as for substitution of bromine benzene. © 1993 Academic Press Ltd.

引用

页码：229 / 235

页数：7

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