STUDY OF C49-TISI2 AND C54-TISI2 FORMATION ON DOPED POLYCRYSTALLINE SILICON USING IN-SITU RESISTANCE MEASUREMENTS DURING ANNEALING

被引:38
作者
CLEVENGER, LA [1 ]
MANN, RW [1 ]
ROY, RA [1 ]
SAENGER, KL [1 ]
CABRAL, C [1 ]
PICCIRILLO, J [1 ]
机构
[1] IBM MICROELECTR,ESSEX JCT,VT 05452
关键词
D O I
10.1063/1.357897
中图分类号
O59 [应用物理学];
学科分类号
摘要
In situ resistance versus temperature or time for reactions between 32 and 57.5 nm of titanium and undoped or doped polycrystalline silicon (boron, arsenic, or phosphorus, 7.9×1019-3.0×10 20/cm3) has been measured and no clear correlation was found between the activation energy for the formation of the industrially important low-resistance C54-TiSi2 phase and its formation temperature. It is also demonstrated that with certain moderate doping levels typical of complementary metal-oxide-semiconductor manufacturing, boron or phosphorus-doped polycrystalline silicon can delay the formation of C54-TiSi2 more than arsenic-doped polycrystalline silicon. Finally, by using in situ resistance measurements, it is demonstrated that the "two-step" thermal annealing process similar to a salicide process requires less thermal annealing time at high temperatures to form C54-TiSi 2 than a single "one-step" thermal anneal at the same temperature. © 1994 American Institute of Physics.
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页码:7874 / 7881
页数:8
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