TRANSITION-METAL STANNYL COMPLEXES .6. CHELATE-ASSISTED OXIDATIVE ADDITION OF SN-C BONDS TO AN IRON CENTER

被引：20

作者：

SCHUBERT, U

GRUBERT, S

SCHULZ, U

MOCK, S

机构：

[1] Institut für Anorganische Chemie, Unlversität Würzburg, W-8700 Würzburg, Am Hubland

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 10期

关键词：

D O I：

10.1021/om00046a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The phenyl stannyl complex (CO)3(Ph)FePPh2CH2CH2SnPh2 (3) is prepared by oxidative addition of a Sn-Ph group of Ph2PCH2CH2SnPh3 (1) by two different routes: reaction of Fe2(CO)9 with 1 via (CO)4FePPh2CH2CH2SnPh3 or reaction of (CO)4Fe(H)SiMePh2 with 1 via (CO)3(H)(MePh2Si)FePPh2CH2CH2SnPh3.

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收藏

页码：3163 / 3165

页数：3

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共 6 条

[1] REACTIVITY OF FE(CO)4(H)SIPH3 FE(CO)4(H)GEPH3 AND MECHANISM OF SUBSTITUTION BY 2-ELECTRON-DONOR LIGANDS - IMPLICATIONS FOR THE MECHANISM OF HYDROSILYLATION OF OLEFINS CATALYZED BY FE(CO)5 [J].

BELLACHIOMA, G ;

CARDACI, G ;

COLOMER, E ;

CORRIU, RJP ;

VIOUX, A .

INORGANIC CHEMISTRY, 1989, 28 (03) :519-525

[2] REACTIVITY OF SMALL-RING MONOSTANNACYCLOALKANES .3. RING-EXPANSION REACTIONS OF 1,1-DIMETHYL-1-STANNACYCLOPENTANE [J].

BULTEN, EJ ;

BUDDING, HA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 166 (03) :339-346

[3] OXIDATIVE ADDITION OF TIN(IV) COMPOUNDS TO ETHYLENE BIS(TRIPHENYLPHOSPHINE)PLATINUM [J].

BUTLER, G ;

EABORN, C ;

PIDCOCK, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 181 (01) :47-59

[4] CHEMISTRY OF THE METAL CARBONYLS .3. THE REACTION BETWEEN IRON PENTACARBONYL AND TETRAORGANOTIN COMPOUNDS [J].

KING, RB ;

STONE, FGA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (15) :3833-3835

[5] PREPARATION, STEREOCHEMISTRY AND REACTIVITY OF HYDRIDOSTANNYL COMPLEXES OF IRON AND CORRESPONDING ANIONIC COMPLEXES [J].

KNORR, M ;

PIANA, H ;

GILBERT, S ;

SCHUBERT, U .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 388 (03) :327-350

[6] TRANSITION-METAL STANNYL COMPLEXES .4. PALLADIUM AND PLATINUM COMPLEXES WITH CHELATING PHOSPHINOALKYLSTANNYL LIGANDS BY OXIDATIVE ADDITION OF SN-C BONDS [J].

MULLER, C ;

SCHUBERT, U .

CHEMISCHE BERICHTE, 1991, 124 (10) :2181-2184