THE ROTATIONAL SPECTRUM OF TERTIARY BUTYL ISOCYANIDE UP TO 730 GHZ - THE OBSERVATION AND CLASSIFICATION OF THE H(3) SPLITTING

被引：22

作者：

CAZZOLI, G ^{[1
]}

COTTI, G ^{[1
]}

DORE, L ^{[1
]}

KISIEL, Z ^{[1
]}

机构：

[1] POLISH ACAD SCI,INST PHYS,PL-02668 WARSAW,POLAND

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1993年 / 162卷 / 02期

关键词：

D O I：

10.1006/jmsp.1993.1298

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The measurements of the rotational spectrum of tertiary butyl isocyanide, (CH3)3CNC, were extended to 730 GHz, J = 124, and K = 90. The new mm-wave and sideband FIR-laser measurements were combined with previous results to yield accurate spectroscopic constants for the whole frequency region 0-730 GHz. In the highest frequency transitions a splitting in the K = 3 lines was observed, allowing the determination of the splitting constant h3. The known values of h3 for C3v-type molecules are compared and empirical rules for their behavior are derived and discussed. © 1993 Academic Press, Inc.

引用

页码：467 / 473

页数：7

共 19 条

[1] CALCULATED SEXTIC CENTRIFUGAL-DISTORTION CONSTANTS OF POLYATOMIC-MOLECULES [J].