SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A STEREOSPECIFIC DINUCLEAR GALLIUM TRIPLE-HELIX - USE OF THE TRANSINFLUENCE IN METAL-ASSISTED SELF-ASSEMBLY

被引：148

作者：

ENEMARK, EJ ^{[1
]}

STACK, TDP ^{[1
]}

机构：

[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 09期

关键词：

ASYMMETRIC SYNTHESES; GALLIUM COMPOUNDS; HELICES; SELF-ASSEMBLY; SUPRAMOLECULAR CHEMISTRY;

D O I：

10.1002/anie.199509961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stereospecific and quantitative assembly of a dinuclear triple helix is achieved by the simple, chiral catecholamide bridging ligand 1 with Ga3+ ions. Structural and spectral characterization show that the stereospecificity of the helix is maintained both in the solid and solution state. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：996 / 998

页数：3

共 31 条

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