HYDROBORATION WITH BORON HALIDES AND TRIALKYLSILANES

被引：66

作者：

SOUNDARARAJAN, R ^{[1
]}

MATTESON, DS ^{[1
]}

机构：

[1] WASHINGTON STATE UNIV,DEPT CHEM,PULLMAN,WA 99164

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 08期

关键词：

D O I：

10.1021/jo00295a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mixtures of alkenes and trialkylsilanes added to boron trichloride at −78°C result in quantitative hydroboration, presumably via dichloroborane, to alkyldichloroboranes, which with trialkylsilanes at 25°C hydroborate alkenes to dialkylchloroboranes. © 1990, American Chemical Society. All rights reserved.

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页码：2274 / 2275

页数：2

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