REACTIONS OF CATECHOLATOBORANE WITH PHOSPHINORHODIUM COMPLEXES - MOLECULAR-STRUCTURES OF [RHHCL(BCAT)(PPRI3)2] AND [((PRI2PCH2)2)RH((ETA-6-CAT)BCAT)] (CAT = 1,2-O2C6H4)

被引：140

作者：

WESTCOTT, SA

TAYLOR, NJ

MARDER, TB

BAKER, RT

JONES, NJ

CALABRESE, JC

机构：

[1] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

[2] DUPONT CO INC,DEPT CENT RES & DEV,EXPTL STN,WILMINGTON,DE 19880

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 05期

关键词：

D O I：

10.1039/c39910000304

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of catecholatoborane (HBcat), 1, to [RhCl(N2)(PPr(i)3)2] gives the first structurally characterised, unsaturated boryl complex, [RhHCl(Bcat)(PPr(i)3)2], whereas reaction of [{(Pr(i)2PCH2)2}Rh(eta-3-2-Me-allyl)] with 2 equiv. of 1 affords [{(Pr(i)2PCH2)2Rh{(eta-6-cat)Bcat}] via B-substituent redistribution; both complexes catalyse the hydroboration of oct-1-ene with 1

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页码：304 / 305

页数：2

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