CATALYTIC PHOTOINDUCED CHARGE-TRANSFER OSMYLATION - A NOVEL PATHWAY FROM ARENES TO CYCLITOL DERIVATIVES

被引：49

作者：

MOTHERWELL, WB

WILLIAMS, AS

机构：

[1] Department of Chemistry, Christopher Ingold Laboratories, University College London, London

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 18期

关键词：

ARENE OXIDATION; CHARGE TRANSFER; CONDURITOLS INOSITOLS; OSMYLATION;

D O I：

10.1002/anie.199520311

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A catalytic, highly stereoselective one‐pot synthesis of inositol and conduritol derivatives (2 and 3, respectively) from benzene (1) and other simple arenes has been achieved by excitation of the charge‐transfer band of the complex between the arene and osmium tetraoxide in the presence of chlorate or bromate anions as oxygen transfer reagents. DMAP = 4‐dimethylaminopyridine. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2031 / 2033

页数：3