TRIS(2-METHOXYPHENYL)BISMUTHANE AS A DEHYDRATING AGENT WITH HIGH TEMPLATE ABILITY - AN EFFICIENT SINGLE-STEP SYNTHESIS OF MACROCYCLIC DIESTERS FROM DIACID ANHYDRIDES AND GLYCOLS

被引：11

作者：

OGAWA, T ^{[1
]}

YOSHIKAWA, A ^{[1
]}

WADA, H ^{[1
]}

OGAWA, C ^{[1
]}

ONO, N ^{[1
]}

SUZUKI, H ^{[1
]}

机构：

[1] KYOTO UNIV,FAC SCI,DEPT CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 14期

关键词：

D O I：

10.1039/c39950001407

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tris(2-methoxyphenyl)bismuthane works as both a mild dehydrating agent and a good template for macrocyclic ester synthesis; prolonged heating of the bismuthane with a dicarboxylic acid anhydride and a glycol in toluene under reflux afforded the corresponding macrocyclic 1:1 diester in moderate to good yields, together with a small amount of a macrocyclic 2:2 tetraester.

引用

页码：1407 / 1408

页数：2

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