NEW CHIRAL AUXILIARY - OPTICALLY-ACTIVE THIOL DERIVED FROM CAMPHOR

被引：24

作者：

HUNG, SM ^{[1
]}

LEE, DS ^{[1
]}

YANG, TK ^{[1
]}

机构：

[1] NATL CHUNGHSING UNIV,DEPT CHEM,TAICHUNG 40227,TAIWAN

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(00)82277-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new camphor based mercapto chiral auxiliary has been prepared, and demonstrated to induce very high chiral inductions in the diastereoselective reductions of alpha-sulfinylketones, in the presence of bivalent Lewis acids.

引用

页码：873 / 876

页数：4

共 15 条

[11] SCOTT JW, 1984, ASYMMETRIC SYNTHESIS, V4, pCH1
[12] REDUCTION OF BETA-HYDROXYSULFOXIDES - APPLICATION TO THE SYNTHESIS OF OPTICALLY-ACTIVE EPOXIDES
SOLLADIE, G
DEMAILLY, G
GRECK, C
[J]. TETRAHEDRON LETTERS, 1985, 26 (04) : 435 - 438
[13] SOLLADIE G, 1981, SYNTHESIS-STUTTGART, P185
[14] ASYMMETRIC OXIDATION OF SULFIDES MEDIATED BY CHIRAL TITANIUM COMPLEXES - MECHANISTIC AND SYNTHETIC ASPECTS
ZHAO, SH
SAMUEL, O
KAGAN, HB
[J]. TETRAHEDRON, 1987, 43 (21) : 5135 - 5144
[15] ZWANEBURG B, 1987, PERSPECTIVES ORGANIC

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