HYDROCARBYL LIGAND DERIVATIVES OF GROUP-6 GROUP-9 HETEROMETALLIC CLUSTERS

被引：29

作者：

COMSTOCK, MC ^{[1
]}

SHAPLEY, JR ^{[1
]}

机构：

[1] UNIV ILLINOIS, SCH CHEM SCI, URBANA, IL 61801 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 1995年 / 143卷

基金：

美国国家科学基金会;

关键词：

GROUP 6-GROUP 9 HETEROMETALLIC CLUSTERS; HYDROCARBON LIGANDS; SYNTHESIS; REACTIVITY;

D O I：

10.1016/0010-8545(95)01140-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and reactivity of group 6-group 9 heterometallic clusters containing hydrocarbon ligands is reviewed. A variety of methods has been employed in the synthesis of this class of clusters. These methods are organized into several general reaction types: metal exchange reactions, the reactions between dinuclear compounds, reactions utilizing mononuclear metal alkylidynes, and condensation reactions with other mononuclear reagents. The reactions of the resulting heterometallic clusters with alkynes, protons and carbon electrophiles, and miscellaneous substitution reactions are discussed. Applications in catalysis are briefly summarized.

引用

收藏

页码：501 / 533

页数：33

相关论文

共 101 条

[1] CHEMISTRY OF POLYNUCLEAR METAL-COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .49. SYNTHESIS OF MIXED-METAL COMPLEXES WITH BONDS BETWEEN CR,MO OR W AND CO, RH, IR OR RE - CRYSTAL-STRUCTURE OF [CRRERH2(MU-3CC6H4ME-4)-(MU-CO)(CO)9(ETA-C9H7)2] [J].

ABAD, JA ;

DELGADO, E ;

GARCIA, ME ;

GROSSEOPHOFF, MJ ;

HART, IJ ;

JEFFERY, JC ;

SIMMONS, MS ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (01) :41-50

[2] CHEMISTRY OF DI-METAL AND TRI-METAL COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .20. COMPLEXATION OF CARBON METAL TRIPLE BONDS WITH LOW-VALENT METAL SPECIES - CRYSTAL-STRUCTURES OF THE BIMETAL COMPLEXES [CRW(MU-CC6H4ME-4)(CO)4(ETA-C5H5)(ETA-C6ME6)] AND [COW(MU-CC6H4ME-4)(CO)3(ETA-C5H5)(ETA-C5ME5)]WI [J].

ABAD, JA ;

BATEMAN, LW ;

JEFFERY, JC ;

MEAD, KA ;

RAZAY, H ;

STONE, FGA ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (09) :2075-2081

[3]

ADAMS RD, 1988, POLYHEDRON, V7, P2251

[4] ALKYLIDYNE-ALKYNE COUPLING REACTIONS - REACTIONS OF MO2CO(CO)7CP2(MU-3-CH) WITH ETC2ET AND PHC2PH [J].

ADAMS, RD ;

BELINSKI, JA .

ORGANOMETALLICS, 1991, 10 (07) :2114-2120

[5]

ADAMS RD, 1985, PROG INORG CHEM, V33, P127

[6] THE ANALOGY BETWEEN ALKENES AND THE DINUCLEAR SPECIES [CORH(MU-CO)2(ETA-C5ME5)2] [RHRH(MU-CO)2(ETA-C5ME5)2] - DYNAMIC NUCLEAR MAGNETIC-RESONANCE, X-RAY CRYSTALLOGRAPHIC, AND EXTENDED-HUCKEL MOLECULAR-ORBITAL STUDIES OF THE BONDING BETWEEN UNSATURATED CORH AND RH2 FRAGMENTS AND THE PENTACARBONYLMOLYBDENUM GROUPAN [J].

BARR, RD ;

GREEN, M ;

HOWARD, JAK ;

MARDER, TB ;

ORPEN, AG ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (12) :2757-2763

[7] ALKENE-LIKE ROTATION OF UNSATURATED RH2 AND CORH FRAGMENTS WHEN BONDED TO MOLYBDENUM PENTACARBONYL - X-RAY CRYSTAL-STRUCTURE OF [MORH2(MU-CO)2(CO)5(ETA-C5ME5)2] [J].

BARR, RD ;

GREEN, M ;

HOWARD, JAK ;

MARDER, TB ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (14) :759-760

[8] CHEMISTRY OF THE METAL-CARBONYLS .82. SYNTHESIS OF COMPLEXES WITH BONDS BETWEEN RHODIUM AND THE SUBGROUP 6 METALS - X-RAY CRYSTAL-STRUCTURE OF [CRRH(MU-CO)2(CO)2(ETA-C5ME5)(ETA-C6H6)] [J].

BARR, RD ;

GREEN, M ;

MARSDEN, K ;

STONE, FGA ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (03) :507-512

[9] CHEMISTRY OF POLYNUCLEAR METAL-COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .75. REACTIONS OF OCTACARBONYLDICOBALT WITH THE SALTS [X][W(=CR)(CO)2(ETA-5-C2B9H9ME2)](X=NET4 OR PPH4 - R = ME, PH, C6H4ME-2, OR C6H4ME-4) - CRYSTAL-STRUCTURE OF [PPH4][CO2W(MU-3-CPH)(CO)8(ETA-5-C2B9H9ME2)].0.5CH2CL2E [J].

BAUMANN, FE ;

HOWARD, JAK ;

MUSGROVE, RJ ;

SHERWOOD, P ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (07) :1891-1897

[10] THE CARBABORANE GROUP ETA-5-C2B9H9ME2 AS A SPECTATOR AND NON-SPECTATOR LIGAND IN DI-METAL AND TRI-METAL COMPLEX CHEMISTRY - X-RAY CRYSTAL-STRUCTURES OF [PPH4][CO2W(MU-3-CPH)(CO)8(ETA-5-C2B9H9ME2)].1/2-CH2CL2, [NET4][FEW(MU-CC6H3ME2-2,6)(CO)5-(ETA-5-C2B9H9ME2)], AND [IRW(MU-CC6H4ME-4)(CO)2(PET3)2(ETA-5-C2B9H9ME2)]T [J].

BAUMANN, FE ;

HOWARD, JAK ;

MUSGROVE, RJ ;

SHERWOOD, P ;

RUIZ, MA ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (24) :1881-1884

← 1 2 3 4 5 6 7 8 9 10 →