HYDROCARBYL LIGAND DERIVATIVES OF GROUP-6 GROUP-9 HETEROMETALLIC CLUSTERS

被引:29
作者
COMSTOCK, MC [1 ]
SHAPLEY, JR [1 ]
机构
[1] UNIV ILLINOIS, SCH CHEM SCI, URBANA, IL 61801 USA
基金
美国国家科学基金会;
关键词
GROUP 6-GROUP 9 HETEROMETALLIC CLUSTERS; HYDROCARBON LIGANDS; SYNTHESIS; REACTIVITY;
D O I
10.1016/0010-8545(95)01140-K
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and reactivity of group 6-group 9 heterometallic clusters containing hydrocarbon ligands is reviewed. A variety of methods has been employed in the synthesis of this class of clusters. These methods are organized into several general reaction types: metal exchange reactions, the reactions between dinuclear compounds, reactions utilizing mononuclear metal alkylidynes, and condensation reactions with other mononuclear reagents. The reactions of the resulting heterometallic clusters with alkynes, protons and carbon electrophiles, and miscellaneous substitution reactions are discussed. Applications in catalysis are briefly summarized.
引用
收藏
页码:501 / 533
页数:33
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