AN ANOMALOUS CASE OF DIASTEREOFACIAL SELECTIVITY IN THE ADDITION OF CHIRAL ALLYLSTANNANES TO BENZALDEHYDE - IS THE INSIDE ALKOXY EFFECT INVOLVED

被引：32

作者：

GUNG, BW

PEAT, AJ

SNOOK, BM

SMITH, DT

机构：

[1] Department of Chemistry, Miami University, Oxford

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(00)79466-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ''inside alkoxy'' effect has been found to be important in the addition of alpha-(alkoxy) allylstannanes to aldehydes in the presence of BF3.Et2O.

引用

页码：453 / 456

页数：4

共 24 条

[21] DIELS-ALDER REACTION OF DIENES HAVING STEREOGENIC ALLYLIC SUBSTITUENTS - CONTROL OF DIASTEREOFACE SELECTIVITY BY THE DIENOPHILE
TRIPATHY, R
FRANCK, RW
ONAN, KD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (10) : 3257 - 3262
[22] AN EVALUATION OF SIGMA-SIGMA-STAR AND TORSIONAL EFFECTS IN THE OSMYLATION AND EPOXIDATION OF 4-TERT-BUTYLMETHYLENECYCLOHEXANE DERIVATIVES
VEDEJS, E
DENT, WH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (17) : 6861 - 6862
[23] REACTIONS OF (ORGANOSTANNYL)LITHIUM AND (ORGANOGERMYL)LITHIUM REAGENTS WITH SOME (ALLYLIC) CYCLOHEX-2-ENYL CHLORIDES
WICKHAM, G
YOUNG, D
KITCHING, W
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (25) : 4884 - 4895
[24] ERYTHRO-SELECTIVE ADDITION OF CROTYLTRIALKYLTINS TO ALDEHYDES REGARDLESS OF THE GEOMETRY OF THE CROTYL UNIT - STEREOSELECTION INDEPENDENT OF THE STEREOCHEMISTRY OF PRECURSORS
YAMAMOTO, Y
YATAGAI, H
NARUTA, Y
MARUYAMA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (23) : 7107 - 7109

← 1 2 3 →