PHYSICAL CHARACTERIZATION OF INCOMPATIBLE BLENDS OF POLYMETHYLMETHACRYLATE AND POLYCAPROLACTONE

被引：29

作者：

IANNACE, S

DELUCA, N

NICOLAIS, L

CARFAGNA, C

HUANG, SJ

机构：

[1] UNIV BASILICATA,DEPT CHEM,I-85100 POTENZA,ITALY

[2] UNIV CONNECTICUT,INST MAT SCI,STORRS,CT 06268

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1990年 / 41卷 / 11-12期

关键词：

17;

D O I：

10.1002/app.1990.070411116

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Blends of polymethylmethacrylate (PMMA) and poly‐ε‐caprolactone (PCL) were prepared and characterized. The analysis of the glass transition temperature indicates no compatibility of the two polymers, which segregated into two distinct phases. The fracture strength of the blends can be explained on the basis of a constitutive model of spheres of PCL embedded in a PMMA matrix. The trend of water sorption confirms the hypothesis of phase segregation of PCL in the glassy matrix of PMMA. Copyright © 1990 John Wiley & Sons, Inc.

引用

页码：2691 / 2704

页数：14

共 17 条

[11] VISCOSITY AND GLASS TEMPERATURE RELATIONS FOR POLYMER-DILUENT SYSTEMS [J].