A CONVENIENT SYNTHESIS OF ISOTHIOCYANATES FROM PRIMARY NITROALKANES

被引：20

作者：

KIM, JN ^{[1
]}

SONG, JH ^{[1
]}

RYU, EK ^{[1
]}

机构：

[1] KOREA RES INST,CHEM TECHNOL,POB 9,TAEJON 305606,SOUTH KOREA

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 08期

关键词：

D O I：

10.1080/00397919408011704

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of primary nitroalkanes with thiourea in the presence of 4-chlorophenyl isocyanate and a catalytic amount of triethylamine in benzene afforded isothiocyanates in moderate yields.

引用

页码：1101 / 1105

页数：5

共 21 条

[1] KINETICS AND MECHANISM OF 1,3-CYCLOADDITIONS OF BENZONITRILE N-OXIDES TO THIOBENZOPHENONES [J].

BATTAGLIA, A ;

DONDONI, A .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1971, (11) :2096-+

[2] 1,3-DIPOLAR CYCLOADDITIONS OF NITRILE OXIDES WITH SULFONYL ISOTHIOCYANATES - NEW SYNTHETIC METHOD FOR 5-SULFONYLIMINO-1,4,2-OXATHIAZOLES [J].

BORSUS, JM ;

LABBE, G ;

SMETS, G .

TETRAHEDRON, 1975, 31 (13-1) :1537-1539

[3] ON THE SCOPE OF ASYMMETRIC NITRILE OXIDE CYCLOADDITIONS WITH OPPOLZERS CHIRAL SULTAM - TOTAL SYNTHESES OF (+)-HEPIALONE, (-)-(1R,3R,5S)-1,3-DIMETHYL-2,9-DIOXABICYCLO[3.3.1]NONANE, AND (-)-(1S)-7,7-DIMETHYL-6,8-DIOXABICYCLO[3.2.1]OCTANE [J].

CURRAN, DP ;

HEFFNER, TA .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (15) :4585-4595

[4] TOTAL SYNTHESIS OF (-)-SPECIONIN [J].

CURRAN, DP ;

JACOBS, PB ;

ELLIOTT, RL ;

KIM, BH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (17) :5280-5282

[5]

CURRAN DP, 1988, ADV CYCLOADDITION, V1, P129

[6]

DICKORE K, 1966, ANGEW CHEM, V78, P1023

[7] SYNTHESIS AND REACTIVITY OF ADAMANTANE-1-CARBONITRILE N-OXIDE [J].

DONDONI, A ;

BATTAGLI.A ;

BARBARO, G ;

GIORGIAN.P .

JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (20) :3196-&

[8] 1,3-DIPOLAR CYCLOADDITION OF CARBON DISULFIDE TO A NITRILE OXIDE [J].

FOYE, WO ;

KAUFFMAN, JM .

JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (07) :2417-&

[9] CYCLOADDITIONS OF CYANOTHIOFORMAMIDES WITH 1,3-DIPOLES [J].

FRIEDRICH, K ;

ZAMKANEI, M .

CHEMISCHE BERICHTE-RECUEIL, 1979, 112 (05) :1873-1878

[10] NITRILE OXIDES .6. SOME NOVEL ADDITION REACTIONS OF AROMATIC NITRILE OXIDES [J].

GRUNDMAN.C ;

FROMMELD, HD .

JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (01) :157-&

← 1 2 3 →