REACTIONS WITH AND IN ANHYDROUS HYDROGEN-FLUORIDE SYSTEMS .8. TRIETHYLAMINE TRISHYDROFLUORIDE - A CONVENIENT REAGENT FOR THE STEREOSELECTIVE SYNTHESIS OF GLYCOSYL FLUORIDES

被引：22

作者：

MIETHCHEN, R

KOLP, G

机构：

[1] Fachbereich Chemie der Universitaet, D-2500 Rostock

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 60卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)82194-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stereoselective fluorinations are effected by bromine-fluorine exchange at glycosyl bromides of the D- and L-series using triethylamine trishydrofluoride. Pyranosyl fluorides of D-xylose, L-arabinose, D-glucose, D-mannose and L-rhamnose derivatives, as well as of D-galacturonic acid esters, have been prepared. The influence of neighbouring groups in the 2-position is considered.

引用

页码：49 / 55

页数：7

共 29 条

[11] PREPARATION OF SOME 2-DEOXY-GLYCOSYL FLUORIDES AND 2,6-DIDEOXY-GLYCOSYL FLUORIDES [J].