THE OZONE SENSITIZED OXIDATIVE CONVERSION OF METHANE TO METHANOL AND ETHANE TO ETHANOL

被引：15

作者：

GESSER, HD

HUNTER, NR

DAS, PA

机构：

[1] Department of Chemistry, University of Manitoba, Winnipeg, R3T 2N2, MB

来源：

CATALYSIS LETTERS | 1992年 / 16卷 / 1-2期

关键词：

METHANE; ETHANE; METHANOL; ETHANOL; OZONE; OXYGEN ATOM; OXIDATION; SENSITIZATION;

D O I：

10.1007/BF00764374

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of O2, O3, and CH4 or C2H6 of 7.76, 0.24 and 92% of the hydrocarbon respectively (residence time of 8.8 min) at 1 atm, and 400-degrees-C for CH4 and 300-degrees-C for C2H6 gave CO, CO2, H2O, CH2O and CH3OH from CH4 and in addition CH4, C2H4, CH3CHO and C2H5OH from C2H6. No reaction occurred when O3 was absent indicating that the partial oxidation was sensitized (initiated) by the oxygen atoms formed by the decomposition of ozone.

引用

页码：217 / 221

页数：5

共 12 条

[1] DIRECT CONVERSION OF ETHANE TO ETHANOL BY THE HOMOGENEOUS PARTIAL OXIDATION AT HIGH-PRESSURES [J].