FROM ARYLIODONIO-QUINOLINE-8-OLATES TO ARYLQUINOLINIUM-8-OLATES BY A 2-STEP ARYL MIGRATION

被引:18
作者
GEORGANTJI, A [1 ]
SPYROUDIS, S [1 ]
机构
[1] UNIV THESSALONIKI,DEPT CHEM,ORGAN CHEM LAB,GR-54006 THESSALONIKI,GREECE
关键词
D O I
10.1016/0040-4039(94)02280-O
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of 4-nitro-8-hydroxyquinoline with (diacetoxyiodo) benzene affords aryliodonio-quinoline-8-olates. Thermal migration of the aryl group from iodine to oxygen and photochemical migration from oxygen to nitrogen leads to the formation of intesively coloured arylquinolinium-8-olates.
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页码:443 / 446
页数:4
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