PHENYLIODONIOPHENOLATES FROM 1,3-DIHYDROXYBENZENE DERIVATIVES

被引:27
作者
SPYROUDIS, S
TARANTILI, P
机构
[1] Laboratory of Organic Chemistry, Chemistry Department, University of Thessaloniki, Thessaloniki
关键词
D O I
10.1016/S0040-4020(01)89291-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new type of phenyliodonio phenolates resulting from the reaction of 1,3-hydroxy benzene derivatives and (diacetoxyiodo)benzene were isolated and characterized. The new phenolates afforded cyclization products from their photochemical reaction with alkenes and alkynes and phenyl ethers from their thermal rearrangement. A possible reaction pathway is proposed in order to explain the regioselectivity of these reactions.
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页码:11541 / 11552
页数:12
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