OXIDATIONS OF SUBSTITUTED PHENOLS WITH HYPERVALENT IODINE - APPLICATIONS TO THE PHTHALIDE ANNULATION ROUTE TO ANTHRAQUINONES

被引：54

作者：

MITCHELL, AS ^{[1
]}

RUSSELL, RA ^{[1
]}

机构：

[1] DEAKIN UNIV,DEPT CHEM SCI,GEELONG,VIC 3217,AUSTRALIA

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 03期

关键词：

OXIDATION; QUINONE MONOACETALS; PHTHALIDE ANIONS; ANTHRAQUINONES;

D O I：

10.1016/0040-4039(93)85123-E

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Substituted phenols are oxidized by phenyliodonium diacetate in methanol to yield either cyclohexa-2,4-dienones or the isomeric 2,5-dienones depending upon the structure of the phenol. Annulation of these oxidation products with the anion of 3-cyanophthalide affords access to a range of anthraquinones not previously accessible by this route.

引用

页码：545 / 548

页数：4

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