RESHAPING OF STAIRCASE VOLTAMMOGRAMS BY DISCRETE SPHERICAL CONVOLUTION

被引：14

作者：

ENGBLOM, SO

OLDHAM, KB

机构：

[1] Department of Chemistry, Trent University, Peterborough

来源：

ANALYTICAL CHEMISTRY | 1990年 / 62卷 / 06期

关键词：

D O I：

10.1021/ac00205a017

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Linear-scan staircase voltammetry and cyclic staircase vol-tammetry generate unsatisfactory current-voltage curves even for reversible electrode processes. A convolution method Is described that converts such curves, obtained at spherical mercury electrodes, Into the classical wave shape that Is familiar from polarography. The plateaus of these waves are horizontal and their heights accurately match theoretical prediction. © 1990, American Chemical Society. All rights reserved.

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页码：625 / 630

页数：6

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