CATALYTIC COMBUSTION OF HYDROGEN - AIR MIXTURES IN STAGNATION FLOWS

被引：44

作者：

IKEDA, H ^{[1
]}

LIBBY, PA ^{[1
]}

WILLIAMS, FA ^{[1
]}

SATO, J ^{[1
]}

机构：

[1] ISHIKAWAJIMA HARIMA HEAVY IND CO LTD,RES INST,KOTO KU,TOKYO 135,JAPAN

来源：

COMBUSTION AND FLAME | 1993年 / 93卷 / 1-2期

关键词：

D O I：

10.1016/0010-2180(93)90088-K

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The interaction between heterogeneous and homogeneous reactions arising when a mixture of hydrogen and air impinges on a platinum plate at elevated temperature is studied. A reasonably complete description of the kinetic mechanism for homogeneous reactions is employed along with a simplified model for heterogeneous reactions. Four regimes are identified depending on the temperature of the plate, on the rate of strain imposed on the flow adjacent to the plate and on the composition and temperature of the reactant stream: (1) surface reaction alone; (2) surface reaction inhibiting homogeneous reaction; (3) homogeneous reaction inhibiting surface reaction; and (4) homogeneous reaction alone. These regimes are related to those found earlier for other chemical systems and form the basis of future experimental investigations of the chemical system considered in the present study.

引用

页码：138 / 148

页数：11