BIPHENYL-BRIDGED METALLOCENES THAT ARE CHIRAL, CONFIGURATIONALLY STABLE, AND FREE OF DIASTEREOMERS

被引：76

作者：

HUTTENLOCH, ME

DIEBOLD, J

RIEF, U

BRINTZINGER, HH

GILBERT, AM

KATZ, TJ

机构：

[1] UNIV CONSTANCE,FAC CHEM,POSTFACH 5560,W-7750 CONSTANCE,GERMANY

[2] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 11期

关键词：

D O I：

10.1021/om00059a024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Formation of diastereomers is precluded when biphenyl-bridged bis(cyclopentadienyls) and transition-metal halides combine to give chiral ansa-metallocenes. These must be symmetrically substituted. Syntheses and X-ray diffraction analyses are reported for four biphenyl-bridged ansa-metallocenes: titanocene dichlorides 17 and 22, zirconocene dichloride 18, and ferrocene 13.

引用

页码：3600 / 3607

页数：8

共 64 条

[11] SYNTHESIS OF PURE RACEMIC ISOMERS OF ANSA-TITANOCENE DICHLORIDES - CONFORMATIONAL PREFERENCES ARE DETERMINED BY SUBSTITUTION PATTERNS ON THE CYCLOPENTADIENYL RINGS
COLLINS, S
HONG, Y
RAMACHANDRAN, R
TAYLOR, NJ
[J]. ORGANOMETALLICS, 1991, 10 (07) : 2349 - 2356
[12] GENERAL SYNTHETIC ROUTES TO CHIRAL, ETHYLENE-BRIDGED ANSA-TITANOCENE DICHLORIDES
COLLINS, S
HONG, YP
TAYLOR, NJ
[J]. ORGANOMETALLICS, 1990, 9 (10) : 2695 - 2703
[13] ADDITIONS OF CHIRAL ALLYLTITANOCENES TO ALDEHYDES - DIASTEREOSELECTIVE SYNTHESIS OF HOMOALLYLIC ALCOHOLS WITH A RECYCLABLE CHIRAL TRANSITION-METAL REAGENT
COLLINS, S
KUNTZ, BA
HONG, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (17) : 4154 - 4158
[14] X-RAY STRUCTURES OF ETHYLENEBIS(TETRAHYDROINDENYL)-TITANIUM AND ETHYLENEBIS(TETRAHYDROINDENYL)-ZIRCONIUM DICHLORIDES - A REVISION
COLLINS, S
KUNTZ, BA
TAYLOR, NJ
WARD, DG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 342 (01) : 21 - 29
[15] CONIA JM, 1970, B SOC CHIM FR, P2981
[16] CHIRAL ORGANOLANTHANIDE COMPLEXES FOR ENANTIOSELECTIVE OLEFIN HYDROGENATION
CONTICELLO, VP
BRARD, L
GIARDELLO, MA
TSUJI, Y
SABAT, M
STERN, CL
MARKS, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (07) : 2761 - 2762
[17] ANSA-METALLOCENE DERIVATIVES .25. SYNTHESIS, CRYSTAL-STRUCTURE AND REACTIONS OF A TETRAMETHYLETHANO-BRIDGED VANADOCENE DICHLORIDE, (CH3)4C2(C5H4)2VCL2
DORER, B
DIEBOLD, J
WEYAND, O
BRINTZINGER, HH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 427 (02) : 245 - 255
[18] ANOMALY IN PALLADIUM-CATALYZED PHENYLETHYNYLATION OF 2,2'-DIHALOBIPHENYLS - FORMATION OF ALKYLIDENEFLUORENES
DOUGHERTY, TK
LAU, KSY
HEDBERG, FL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (26) : 5273 - 5280
[19] STEREOSELECTIVITY IN THE SYNTHESIS OF TETRAMETHYLETHANO-BRIDGED 3,3'-DI-TERT-BUTYLTITANOCENE DICHLORIDE
ERICKSON, MS
FRONCZEK, FR
MCLAUGHLIN, ML
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 415 (01) : 75 - 85
[20] CRYSTAL-STRUCTURES AND STEREOSPECIFIC PROPYLENE POLYMERIZATIONS WITH CHIRAL HAFNIUM METALLOCENE CATALYSTS
EWEN, JA
HASPESLAGH, L
ATWOOD, JL
ZHANG, HM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (21) : 6544 - 6545

← 1 2 3 4 5 6 7 →