FOURIER-TRANSFORM EMISSION-SPECTROSCOPY OF SCN

被引：45

作者：

RAM, RS ^{[1
]}

BERNATH, PF ^{[1
]}

机构：

[1] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1992年 / 96卷 / 09期

关键词：

D O I：

10.1063/1.462628

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The near-infrared electronic emission spectrum of ScN has been observed in the 1.6-1.8-mu-m spectral region using a Fourier transform spectrometer. The three bands with origins at 5820.0944(5), 6051.2858(20), and 6266.1290(13) cm-1 have been assigned as the 0-0, 1-1, and 2-2 bands of the A (1)SIGMA+ X (1)SIGMA+ electronic transition. The principal equilibrium molecular constants for the ground state obtained from a fit of the observed lines are B(e)" = 0.554 609(17) cm-1, r(e)" = 1.687 23 (3) angstrom and the corresponding values for the excited state are B(e)' = 0.549 277 (17) cm-1, r(e)' = 1.695 40(3) angstrom. Although ScN is a well-known refractory solid, our work is the first observation of the gas-phase ScN molecule.

引用

页码：6344 / 6347

页数：4