INTRAMOLECULAR LEWIS ACID-CATALYZED ASYMMETRIC HETERO-DIELS-ALDER REACTIONS WITH DIENES BEARING CHIRAL SULFINYL GROUPS

被引：21

作者：

HIROI, K

UMEMURA, M

FUJISAWA, A

机构：

[1] Department of Synthetic Organic Chemistry, Tohoku College of Pharmacy, Aoba-Ku, Sendai, Miyagi, 981

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 47期

关键词：

D O I：

10.1016/S0040-4039(00)60862-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A chiral alpha-sulfinyl alpha,beta-unsaturated ketone served as a chiral diene in intramolecular Lewis acid-catalyzed asymmetric cycloaddition reactions, giving hetero-Diels-Alder reaction products along in some cases with ene reaction products in high optical yields. The reaction pathways for Diels-Alder or ene reactions were readily controlled depending on the Lewis acids used.

引用

页码：7161 / 7164

页数：4

共 18 条

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