PREPARATION AND STRUCTURE OF DICHLOROPALLADIUM(II) COMPLEXES OF STERICALLY PROTECTED DIPHOSPHINIDENECYCLOBUTENES AND THEIR SYNTHETIC APPLICATION AS HOMOGENEOUS CATALYST

被引：57

作者：

TOYOTA, K ^{[1
]}

MASAKI, K ^{[1
]}

ABE, T ^{[1
]}

YOSHIFUJI, M ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,AOBA KU,SENDAI,MIYAGI 98077,JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 03期

关键词：

D O I：

10.1246/cl.1995.221

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sterically protected 3,4-bis[(2,4,6-tri-t-butylphenyl)phosphinidene]cyclobutenes reacted with bis(acetonitrile)dichloropalladium(II) to give the corresponding dichloropalladium complexes and the structure of one of the complexes was confirmed by X-ray crystallography. The complexes were utilized as a homogeneous catalyst in the coupling reaction of trimethylsilylacetylene and 1-bromo-4-nitrobenzene.

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页码：221 / 222

页数：2

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