SYNTHETIC STUDIES ON QUASSINOIDS - TOTAL SYNTHESIS OF (+/-)-SHINJULACTONE-C

被引：15

作者：

COLLINS, JL ^{[1
]}

GRIECO, PA ^{[1
]}

GROSS, RS ^{[1
]}

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 23期

关键词：

D O I：

10.1021/jo00310a009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The total synthesis of the novel quassinoid Shinjulactone C (1) is detailed which proceeds via pentacyclic lactone 3 and features new protocols for elaboration of the ring A 1β-hydroxy-2-oxo-Δ3’4olefin unit and the C(8), C(111) bridged hemiketal array which are present in 3 and common to numerous quassinoids. © 1990, American Chemical Society. All rights reserved.

引用

页码：5816 / 5818

页数：3

共 12 条

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[8] SYNTHESIS OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS BY PALLADIUM(II)-CATALYZED DEHYDROSILYLATION OF SILYL ENOL ETHERS
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