APPLICATION OF THE SAEGUSA OXIDATION TO TRIMETHYLSILYL ETHERS OF DIOSPHENOLS

被引:13
作者
KIM, M
APPLEGATE, LA
PARK, OS
VASUDEVAN, S
WATT, DS
机构
[1] UNIV KENTUCKY, DEPT CHEM, DIV MED CHEM, LEXINGTON, KY 40506 USA
[2] UNIV KENTUCKY, LUCILLE PARKER MARKEY CANC CTR, LEXINGTON, KY 40506 USA
关键词
D O I
10.1080/00397919008052802
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The Saegusa oxidation of trimethylsilyl ethers of diosphenols provided enediones and served as a key reaction in the conversion of Δ2-picrasin B to iβ-hydroxy-12-methoxy-picrasa-3,12-diene-2,11-dione, a model for the A ring functionality of many quassinoids. © 1990, Taylor & Francis Group, LLC. All rights reserved.
引用
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页码:989 / 997
页数:9
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