EXOTIC STATES IN THE E-E JAHN-TELLER PROBLEM

被引:12
作者
EIERMANN, H
WAGNER, M
机构
[1] Institut für Theoretische Physik, Universität Stuttgart, 7000 Stuttgart 80
关键词
D O I
10.1063/1.462812
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Fulton-Gouterman transformation is applied to the dynamical E-e Jahn-Teller problem. This approach leads to an unconventional way of visualizing the exact eigensolutions of the problem. It turns out that in the upper energy region, eigenfunctions with unexpected behavior make their appearance ("exotic states"). They practically have no distortion in the oscillatory subspace, whereas eigenfunctions of large radial oscillatory displacement are found in their immediate energetic neighborhood. In a rough way, these exotic states may be related to the "Slonczewski resonances."
引用
收藏
页码:4509 / 4517
页数:9
相关论文
共 26 条
[11]  
KONGETER A, 1990, J CHEM PHYS, V92, P4003, DOI 10.1063/1.457814
[12]   STUDIES OF THE JAHN-TELLER EFFECT .2. THE DYNAMICAL PROBLEM [J].
LONGUETHIGGINS, HC ;
OPIK, U ;
PRYCE, MHL ;
SACK, RA .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1958, 244 (1236) :1-16
[13]  
LUSHCHIK CB, 1982, EXITONS
[14]   TUNNELING PROCESS FROM FREE STATE TO SELF-TRAPPED STATE OF EXCITON [J].
NASU, K ;
TOYOZAWA, Y .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1981, 50 (01) :235-245
[15]   REDUCTION FACTORS FOR DYNAMIC JAHN-TELLER SYSTEMS IN STRONG COUPLING [J].
OBRIEN, MCM ;
POOLER, DR .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1979, 12 (02) :311-320
[16]   WAVEFUNCTIONS FOR DYNAMIC JAHN-TELLER SYSTEMS [J].
OBRIEN, MCM .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1976, 9 (12) :2375-2382
[17]  
POOLER DR, 1984, DYNAMICAL JAHN TELLE
[18]  
REIK HG, 1984, DYNAMICAL JAHN TELLE
[19]   THEORY OF DYNAMICAL JAHN-TELLER EFFECT [J].
SLONCZEWSKI, JC .
PHYSICAL REVIEW, 1963, 131 (04) :1596-&
[20]  
SLONCZEWSKI JC, 1967, RC1777 IBM RES PAP