A NEW STEREOSELECTIVE SYNTHESIS OF (Z)-VINYLSILANE ALLYLIC ALCOHOLS

被引：57

作者：

KIM, KD ^{[1
]}

MAGRIOTIS, PA ^{[1
]}

机构：

[1] W VIRGINIA UNIV, DEPT CHEM, MORGANTOWN, WV 26506 USA

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(00)97007-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new, highly stereoselective method for the synthesis of (Z)-vinylsilane allylic alcohols 3 is described. This approach to such γ-silylated allylic alcohols employs a novel 1,4-0→sp2C silyl rearrangement of appropriate silyl ether precursors 2. © 1990.

引用

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页码：6137 / 6140

页数：4

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