ACCURATE DETERMINATION OF THE EXTENT TO WHICH THE S(E)2' REACTIONS OF AN ALLENYLSILANE ARE STEREOSPECIFICALLY ANTI

被引：36

作者：

BUCKLE, MJC ^{[1
]}

FLEMING, I ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(00)77620-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The allenylsilane 1 has been prepared in high enantiomeric purity (98% e.e.); its S(E)2' reactions with adamantyl chloride and isobutyraldehyde are stereospecifically anti to a very high degree (>99:1).

引用

页码：2383 / 2386

页数：4

共 34 条

[1] IMPROVED PROCEDURE FOR THE ASYMMETRIC REDUCTION OF PROCHIRAL KETONES BY B-(3-PINANYL)-9-BORABICYCLO[3.3.1]NONANE
BROWN, HC
PAI, GG
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (08) : 1606 - 1608
[2] ACCURATE DETERMINATION OF THE EXTENT TO WHICH AN SE2' REACTION OF AN ALLYLSILANE IS ANTI
BUCKLE, MJC
FLEMING, I
GIL, S
[J]. TETRAHEDRON LETTERS, 1992, 33 (31) : 4479 - 4482
[3] CHIRAL ALLENES ARE RACEMIZED BY ORGANOCUPRATES
CLAESSON, A
OLSSON, LI
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (12) : 524 - 525
[4] ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETIC ACID, A VERSATILE REAGENT FOR DETERMINATION OF ENANTIOMERIC COMPOSITION OF ALCOHOLS AND AMINES
DALE, JA
DULL, DL
MOSHER, HS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (09) : 2543 - &
[5] SCOPE AND STEREOCHEMICAL COURSE OF THE ADDITION OF (TRIMETHYLSILYL)ALLENES TO KETONES AND ALDEHYDES - A REGIOCONTROLLED SYNTHESIS OF HOMOPROPARGYLIC ALCOHOLS
DANHEISER, RL
CARINI, DJ
KWASIGROCH, CA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (20) : 3870 - 3878
[6] STEREOCONTROL IN ORGANIC-SYNTHESIS USING SILICON-COMPOUNDS
FLEMING, I
[J]. PURE AND APPLIED CHEMISTRY, 1990, 62 (10) : 1879 - 1886
[7] SYNTHESIS OF ALLENYLSILANES FROM PROPARGYL CARBAMATES
FLEMING, I
TAKAKI, K
THOMAS, AP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (10): : 2269 - 2273
[8] STEREOSPECIFIC SYNTHESES AND REACTIONS OF ALLYL-SILANE AND ALLENYL-SILANE
FLEMING, I
TERRETT, NK
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 264 (1-2) : 99 - 118
[9] Fleming I., 1989, SELECTIVITIES LEWIS, P265
[10] OPTICALLY-ACTIVE ALLYLSILANES .3. ANTI STEREOCHEMISTRY IN PROTODESILYLATION OF AN OPTICALLY-ACTIVE ALLYLSILANE WITH TRIFLUOROACETIC ACID-D
HAYASHI, T
ITO, H
KUMADA, M
[J]. TETRAHEDRON LETTERS, 1982, 23 (44) : 4605 - 4606

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