DIURNAL HO2 CYCLES AT CLEAN-AIR AND URBAN SITES IN THE TROPOSPHERE

We have determined HO2 concentrations at two Oregon sites for continuous periods of 36 to 48 hours, using fluorescence assay with gas expansion. At the sea level coastal site (45-degrees-N 124-degrees-W), NNW winds prevailed during daytime, and a point measurement of very low total nonmethane hydrocarbon concentration indicated the presence of remote tropospheric air of oceanic origin. At the urban site, HO2 was determined during moderately low ozone pollution levels. At both sites, maximum daily [HO2] was in the range of 1-2x10(8) cm-3 under clear-sky conditions, with an estimated overall uncertainty of 40%. HO2 was detected by continuous low-pressure sampling with flowing chemical conversion to HO, which was detected by laser-excited fluorescence. The instrumental response to HO2 was calibrated by the self-decay of HO2 at atmospheric pressure. Interference in the measured daytime HO2 concentrations by RO2 was estimated at less than 20%.