POLYPYRROLE FILM FORMATION BY SOLUTION-SURFACE ELECTROPOLYMERIZATION - INFLUENCE OF SOLVENTS AND DOPED ANIONS

被引：25

作者：

LEE, S ^{[1
]}

SUNG, H ^{[1
]}

HAN, S ^{[1
]}

PAIK, W ^{[1
]}

机构：

[1] SOGANG UNIV,DEPT CHEM,SEOUL 121742,SOUTH KOREA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 04期

关键词：

D O I：

10.1021/j100055a034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pyrrole was found to be polymerized to conducting polypyrrole by solution-surface (SS) electropolymerization in which the polymerization occurs along the solution-gas interface or along the interface between aqueous and nonaqueous solvents. The SS polymerization of pyrrole was observed to occur with various electrolytes in aqueous solutions in contact with a gas phase or an organic phase. Conditions favorable for SS polymerization were examined. The SS polymerization seemed to require, among other things, a large surface (interfacial) tension of the solvent which is a prerequisite for surface excess of the monomer at the interface.

引用

页码：1250 / 1252

页数：3

共 8 条

[1]

Diaz A.F., 1986, HDB CONDUCTING POLYM, V1

[2] EFFECT OF THE TEMPERATURE OF SYNTHESIS ON THE CONDUCTIVITY AND ELECTROCHEMICAL-BEHAVIOR OF POLYANILINE [J].