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GRAFT-COPOLYMERS OF METHACRYLIC-ACID AND SBS AND K-RESIN BY THE ANTHRACENE PHOTOSENSITIZED FORMATION OF HYDROPEROXIDES
被引:18
作者:
DONG, XX
GEUSKENS, G
WILKIE, CA
机构:
[1] MARQUETTE UNIV,DEPT CHEM,MILWAUKEE,WI 53233
[2] FREE UNIV BRUSSELS,B-1050 BRUSSELS,BELGIUM
关键词:
D O I:
10.1016/0014-3057(95)00084-4
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
The sorption of anthracene from a methanolic solution into SBS and K-resin has been studied. More anthracene may be sorbed into K-resin than into SBS; this is surprising since the free volume will be in the butadiene phase and SBS contains substantially more butadiene than does K-resin. For both polymers, photolysis generates singlet oxygen and hydroperoxides in the butadiene region. The effects of anthracene and methacrylic acid concentration, time and temperature have been investigated.
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页码:1165 / 1168
页数:4
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