ELECTROSTATIC INTERACTION EFFECTS ON THE RATE OF REDUCTIVE POLYMERIZATION FOR VINYLBIPYRIDINE-CONTAINING METAL-COMPLEXES

被引：6

作者：

BALDY, CJ ^{[1
]}

MORRISON, DL ^{[1
]}

ELLIOTT, CM ^{[1
]}

机构：

[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

来源：

LANGMUIR | 1991年 / 7卷 / 10期

关键词：

D O I：

10.1021/la00058a067

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of mixed ligand metal complexes containing the electrochemically polymerizable ligand 4-methyl-4'-vinyl-2,2'-bipyridine (vbpy) have been prepared and their electrochemical polymerization has been studied as a function of formal oxidation state. The complexes chosen for this study were initially either neutral or 1+ charged prior to electrochemical reduction. This is in contrast to previously studied complexes containing vbpy ligands, most of which have been initially 2+ charged. The results of this study confirm our earlier suggestion that the existence of a net electrostatic charge on polymerizing vbpy metal monomer complexes reduces the rate of electrochemically induced polymer formation.

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页码：2376 / 2379

页数：4

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