LIGHT-RESPONSIVE METAL ENCAPSULATION IN CALIX[4]ARENE

被引：31

作者：

DENG, G ^{[1
]}

SAKAKI, T ^{[1
]}

NAKASHIMA, K ^{[1
]}

SHINKAI, S ^{[1
]}

机构：

[1] ERATO RES DEV CORP JAPAN, CHEMIRECOGN PROJECT,FUKUOKA IND TECHNOL CTR, 332-1 KAMIKOGA,CHIKUSHINO, FUKUOKA 818, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 07期

关键词：

D O I：

10.1246/cl.1992.1287

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An ionophoric calix[4]arene (1), in which the metal-binding ability is photochemically controlled, was designed by introducing two anthracenes near the metal-binding site. Compound 1 itself showed the poor ion affinity and the poor ion selectivity whereas photochemically-produced isomer showed the much improved ion affinity and the sharp Na+ selectivity.

引用

页码：1287 / 1290

页数：4