THE STRUCTURE OF A MODEL IONIC MELT IN A PLANAR SLIT

被引：7

作者：

BRATKO, D ^{[1
]}

BLUM, L ^{[1
]}

BHUIYAN, LB ^{[1
]}

机构：

[1] UNIV PUERTO RICO,DEPT PHYS,RIO PIEDRAS,PR 00931

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 94卷 / 01期

关键词：

D O I：

10.1063/1.460323

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structure of the primitive model fused salt in planar slit is studied by Monte Carlo simulation. The density profile of the ionic melt in the slit with respect to the walls displays oscillations similar to those observed with simple liquids. At the pore width of about seven ionic diameters, the pressure exerted on the walls is comparable to the virial pressure of the bulk melt. The calculated surface energy of 210 + 20 mN m-1 is close to the experimental value for molten potassium chloride at similar conditions.

引用

页码：586 / 589

页数：4