PREPARATION OF MESO-TETRA(4-GALVINOLPHENYL)PORPHYRIN - A BUILDING-BLOCK FOR MOLECULAR MAGNETIC-MATERIALS

被引:8
作者
SHULTZ, DA
KNOX, DA
MORGAN, LW
SANDBERG, K
TEW, GN
机构
[1] Department of Chemistry, North Carolina State University Raleigh, NC 27695-8204
关键词
D O I
10.1016/S0040-4039(00)60593-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis and oxidative electrochemistry of a free-radical substituted metalloporphyrin are described. The porphyrin is prepared in four steps in good yield. Oxidation at a platinum electrode shows the molecule undergoes five reversible one-electron transfers to a stable pentaradical.
引用
收藏
页码:3975 / 3978
页数:4
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