PHOTOCHEMICAL DESULFURIZATION OF INDOLINE-2-THIONES

被引：12

作者：

NISHIO, T

OKUDA, N

KASHIMA, C

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 01期

关键词：

D O I：

10.1039/p19910000141

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photochemical reactions of indoline-2-thiones in the presence of amines have been examined. Irradiation of indoline-2-thiones 1 in the presence of triethylamine yielded the desulphurization products, indolines 2, along with N,N-diethylthioacetamide 3. The photodesulphurization reactions of indoline-2-thiones 1 can be explained by a sequential electron/proton-transfer mechanism from the amine to the excited indoline-2-thione.

引用

页码：141 / 143

页数：3

共 22 条

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