ACI-NITRODIPHENYLMETHANE - A HYDROGEN-BONDED DIMER

被引：19

作者：

BOCK, H

DIENELT, R

SCHODEL, H

HAVLAS, Z

HERDTWECK, E

HERRMANN, WA

机构：

[1] CZECHOSLOVAK ACAD SCI, INST ORGAN CHEM & BIOCHEM, CS-16610 PRAGUE, CZECHOSLOVAKIA

[2] TECH UNIV MUNICH, INST ANORGAN CHEM, D-85748 GARCHING, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1993年 / 32卷 / 12期

关键词：

D O I：

10.1002/anie.199317581

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first structurally characterized aci‐nitromethane, the title compound, was obtained by acidifying its sodium salt. It crystallized as the hydrogen‐bonded dimer 1. The eight‐membered ring that includes the H bonds has a chair conformation. According to quantum mechanical calculations, the cooperative effect on the formation of the H‐bonded dimer is 40%. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1758 / 1760

页数：3

共 21 条

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