APPROACHES TO WATER-SOLUBLE PHOSPHINES .2. FREE-RADICAL ADDITION-REACTIONS OF PHENYLPHOSPHINES

被引：30

作者：

HEESCHEWAGNER, K ^{[1
]}

MITCHELL, TN ^{[1
]}

机构：

[1] UNIV DORTMUND,FACHBEREICH CHEM,POSTFACH 500500,W-4600 DORTMUND 50,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 468卷 / 1-2期

关键词：

PHOSPHINE; WATER SOLUBLE PHOSPHINES; RADICAL ADDITION; CHIRALITY;

D O I：

10.1016/0022-328X(94)80036-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Free radical additions of diphenylphosphine, phenylphosphine and ethylenebis(phenylphosphine) to the following species are described: alkynols, alkyne ethers, unsaturated carboxylic acids and esters and beta-lactones. In a number of cases, these lead to water-soluble phosphines. NMR spectroscopic characterization of all new products has been carried out.

引用

页码：99 / 106

页数：8

共 30 条

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