Studies towards a postulated biomimetic Diels-Alder reaction for the synthesis of himgravine

被引：62

作者：

Baldwin, JE ^{[1
]}

Chesworth, R ^{[1
]}

Parker, JS ^{[1
]}

Russell, AT ^{[1
]}

机构：

[1] OXFORD CTR MOLEC SCI, OXFORD OX1 3QY, ENGLAND

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 52期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0040-4039(95)02045-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The possible role of an iminium ion mediated Diels-Alder reaction on the biosynthetic pathway to himgravine is discussed. The results of a preliminary investigation of a related oxycarbenium ion mediated Diels-Alder reaction are reported and are in accord with the stereochemistry of the natural product.

引用

页码：9551 / 9554

页数：4

共 17 条

[1]

BENNETT PAR, 1988, THESIS U OXFORD UK

[2] CONTROL OF STERIC COURSE OF WITTIG REACTION - STEREOCHEMICAL STUDIES AND SYNTHETIC APPLICATIONS [J].