OPTICALLY-ACTIVE REFERENCE COMPOUNDS FOR ENVIRONMENTAL-ANALYSIS OBTAINED BY PREPARATIVE ENANTIOSELECTIVE GAS-CHROMATOGRAPHY

被引：10

作者：

KONIG, WA ^{[1
]}

HARDT, IH ^{[1
]}

GEHRCKE, B ^{[1
]}

HOCHMUTH, DH ^{[1
]}

HUHNERFUSS, H ^{[1
]}

PFAFFENBERGER, B ^{[1
]}

RIMKUS, G ^{[1
]}

机构：

[1] LEBENSMITTEL & VET UNTERSUCHUNGSAMT LANDES SCHLES,D-24537 NEUMUNSTER,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 20期

关键词：

D O I：

10.1002/anie.199420851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A modified cyclodextrin stationary phase was used in the resolution of the enantiomers of the cyclodiene insecticides cis‐ and trans‐chlordane, oxychlordane, heptachlor, and other metabolized xenobiotics on a milligram scale by preparative gas chromatography. Enantiomeric excesses of between 42 and >99% were obtained. The enantiomerically pure (or enriched) compounds can be used in studies into the enantioselective degradation of toxic substances present in the environment. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2085 / 2087

页数：3

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