A NEW SYNTHESIS OF 2-FLUORO-1-OLEFINS

被引：44

作者：

MCCARTHY, JR

MATTHEWS, DP

BARNEY, CL

机构：

[1] Merrell Dow Research Institute, Cincinnati, OH 45215

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 07期

关键词：

D O I：

10.1016/S0040-4039(00)94406-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first examples of the addition of PhSeF to olefins to yield β-fluoro phenylselenides (2) are reported. β-Fluoro phenylselenides (2) obtained from terminal olefins were converted to the title vinyl fluorides 3 on treatment with ozone, whereas, 2 obtained from internal and cyclic olefins formed allyl fluorides. This method provides an entry to previously unreported 2-benzyl-2-fluoro-1-olefins (e.g. 3i). © 1990.

引用

页码：973 / 976

页数：4

共 33 条

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