NEW LIPOPHILIC AIR-STABLE SILANETRIOLS - FIRST EXAMPLE OF AN X-RAY CRYSTAL-STRUCTURE OF A SILANETRIOL WITH SI-N BONDS

被引：83

作者：

MURUGAVEL, R ^{[1
]}

CHANDRASEKHAR, V ^{[1
]}

VOIGT, A ^{[1
]}

ROESKY, HW ^{[1
]}

SCHMIDT, HG ^{[1
]}

NOLTEMEYER, M ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 11期

关键词：

D O I：

10.1021/om00011a054

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By using hindered primary aromatic amines, the four silanetriols RN(SiMe(3))(Si(OH)(3)) (R = 2,6-Me(2)C(6)H(3) (2b), 2,4,6-Me(3)C(6)H(2) (2c), 2-i-Pr-6-MeC(6)H(3) (2d), 2,6-i-Pr2C6H3 (2e)) have been synthesized. These N-bonded silanetriols, apart from being air-stable, are also highly lipophilic, being soluble in a variety of organic solvents. The crystal structure of 2c has been determined and represents a new structural form for silanetriols.

引用

页码：5298 / 5301

页数：4

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