DIRECT TRIFLUOROMETHYLTHIOLATION OF ARYL HALIDES USING METHYL FLUOROSULFONYLDIFLUOROACETATE AND SULFUR

被引：70

作者：

CHEN, QY

DUAN, JX

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 11期

关键词：

D O I：

10.1039/c39930000918

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of S8 and copper(I) iodide, methyl fluorosulfonyldifluoroacetate 1 reacts with aryl halides 2 in hexamethylphosphoramide (HMPA) or N-methylpyrrolidinone (NMP) at 100-110-degrees-C to give the corresponding trifluoromethylthiolated derivatives 3 in good yields.

引用

页码：918 / 919

页数：2