SILICON-TETHERED RADICAL CYCLIZATION AND INTRAMOLECULAR DIELS-ALDER STRATEGIES ARE COMBINED TO PROVIDE A READY ROUTE TO HIGHLY FUNCTIONALIZED DECALINS

被引：28

作者：

LOPEZ, JC ^{[1
]}

GOMEZ, AM ^{[1
]}

FRASERREID, B ^{[1
]}

机构：

[1] DUKE UNIV,DEPT CHEM,PAUL M GROSS CHEM LAB,DURHAM,NC 27708

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 09期

关键词：

D O I：

10.1039/c39930000762

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stereoselective addition of carbon branches at C(1) and C(2) Of L-rhamnal is achieved via silicon-mediated radical procedures, and the product is readily processed to give a hex-2-enopyranosid-4-ulose whose intramolecular Diels-Alder reaction has been examined.

引用

页码：762 / 764

页数：3

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