COMPLETE PI-FACIAL STEREOSELECTIVITY IN THE TICL4-MEDIATED [4+2] CYCLOADDITION OF CYCLOPENTADIENE TO N,N'-FUMAROYLDI[(2R)-BORNANE-10,2-SULTAM]

被引：15

作者：

CHAPUIS, C

RZEPECKI, P

BAUER, T

JURCZAK, J

机构：

[1] POLISH ACAD SCI,INST ORGAN CHEM,PL-01224 WARSAW,POLAND

[2] UNIV WARSAW,DEPT CHEM,PL-02093 WARSAW,POLAND

来源：

HELVETICA CHIMICA ACTA | 1995年 / 78卷 / 01期

关键词：

D O I：

10.1002/hlca.19950780114

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under the co-operative influence of two prosthetic groups, and independent of the TiCl4 concentration, complete and constant diastereofacial pi-selection was achieved during the [4 + 2] cycloaddition of cyclopentadiene to N,N'-fumaroyl-di[(2R)-bornane-10,2-sultam] ((-)-1c); reactive conformations are discussed.

引用

页码：145 / 150

页数：6

共 111 条

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